Nitro, poly, and more: what they’re made of, and why we love them.
In previous columns, I’ve touched on the subject of lacquer checking and the rise of relic finishes, but I thought a discussion of finishing materials might be in order as well. The terms nitro, poly, and lacquer, as well as other vague descriptions, are often used, and just as often, they’re misused and misunderstood. While I’m not a chemist and don’t pretend to know everything about coatings, I’ll try to outline some basic facts and how they relate to your guitar’s look, sound, and durability. But first, a little history.
Possibly the oldest decorative coatings are red and black lacquers from China that date back thousands of years. Chinese lacquer was primarily used to beautify luxury goods. Early lacquers were made from tree sap mixed with other organic ingredients for color and stability.
Shellac, made from the sticky secretions of the tiny lac insect, appeared in Asia and India around 1200 BCE. In the 17th century, shellac became popular in Europe among furniture and instrument makers. (Fun fact: It can take up to 90,000 insects to produce one pound of shellac.)
The word “lacquer” is a catch-all term for coatings made from resins, including tree pulp, sap, and chemically manufactured synthetics. These resins can be diluted with solvents, but not water. However, there is now a class of water-soluble finishes that are referred to as waterborne lacquer. Confusing, isn’t it?
For practical purposes, let’s divide coatings into two groups: thermoplastic, which cures by drying (solvent evaporation), and thermoset, which cures by a chemical reaction alone. All of these finishes are diluted with solvent in order to allow them to be sprayed or applied by a brush. A thermoplastic coating will release the carrier solvents over time, leaving the solid material behind. This can take from a few days to several weeks depending on the lacquer’s particular formulation and the temperature and humidity of the paint room.“While back in the day it was difficult for builders to find suitable coatings that didn’t check, today it’s hard to find a lacquer that will.”
Nitrocellulose lacquer is thermoplastic. Made from trees, it’s loved for its ease of use, warm feel, and attractive sheen. To visualize the finishing process, think of thermoplastic like mud. Dirt (solids) plus water (solvent) equals mud. It’s easy to smear it on a surface, and when the water evaporates, it’s a somewhat hard finish. If you put water on your dried surface, it becomes mud again. In a similar way, a thermoplastic finish never completely cures. Nitro lacquer is able to be repaired easily with more nitro. The solvents in the repair material soften the original finish and they “melt” together. This also makes these finishes susceptible to damage from certain aggressive solvent-based cleaners like alcohol or turpentine.
Thermoset finishes, like polyester and catalyzed polyurethane, are for the most part impervious to most solvents because they are chemically cured. Thermoset coatings are typically two- or three-part mixtures which, when combined before application, react chemically (catalyze) to harden. Once they “lock,” they are set indefinitely. Anyone who has mixed two-part epoxy will be familiar with this process. While more difficult to repair, damaged thermoset finishes can be fixed with proper surface prep. Although the edge of a spot repair on a thermoset finish can be hard to disguise, some modern cyanoacrylate (superglue) repairs can be practically invisible. The ability to mass-produce thermoset chemicals, and their fast curing cycle, has made it the leading type of finishing material for the auto industry starting in the 1950s, and the guitar industry in the 1970s.
Another appeal of thermosets from a manufacturing standpoint is resistance to chipping and cold checking. During the guitar boom of the 1960s, lacquer checking was such a concern that many factories moved to catalyzed thermoset finishes. These are sometimes called “polys,” but they actually encompass a wide variety of products including polyesters, catalyzed urethanes, and two-stage conversion varnishes. Although guitarists have recently embraced the beauty of this “defect,” most manufacturers of new instruments have switched to finishes in the thermoset family to avoid it. The downside is that some can feel sticky, especially on necks.
The truth of the matter is that today, even nitrocellulose lacquers are blended with enough additives that they can be hard to cold check. Which brings us to the relic aesthetic. While back in the day it was difficult for builders to find suitable coatings that didn’t check, today it’s hard to find a lacquer that will.
There’s really more to this story than space will allow. We haven’t touched upon acrylics, conversion varnishes, epoxies, and French polish variants, let alone the question of whether or not finishes affect sound. That’s for another day, but for now, you know that finish type makes a practical difference that you can see and feel.
A lot of you have been waiting for this penultimate step of our guitar aging project, so let’s do some damage!
Welcome back to Mod Garage. Today we’ll continue to work on our aging project, and some of you might be wondering why there was such a long break. The reason is simple: suboptimal timing from my side. The last part of this column was in the middle of autumn, and I wanted you to do the following steps outside (if possible) and not on the kitchen table. Wintertime is not the best time for such a challenge but now is a good starting point, so let’s go!
We’re almost done with our project, can you believe it? In this installment, we’ll take care of the color, talk about fading, and we’ll crack the lacquer—something a lot of you have been waiting for—before we add some dings and dongs in the last part of this series, which is the final touch before we put it all together again.a
We also have an advice column on aging from my friend and colleague Matthias “Matti” Meyer, from the German-based Bassart Guitars. Matti is one of the best pro agers I know. Please follow his advice and recipe for aging wood at the end of this column—we will need these tools in the next and final part of this project.
Aging the Color
Over time, the colors on guitar bodies start to fade, and depending on the type of color and the paint-job method itself, discolorations can show up. The two main factors are if the guitar was exposed to ultraviolet light and if the paint job is all intact. A famous example is the Gibson Les Paul goldtop guitars with the golden color turning greenish, or the Gibson sunburst Les Pauls losing the red color of the sunburst spray job over time. But Fender guitars also suffer similar problems.
What we want to mimic is an old nitro lacquer, but with our Harley Benton guitar we have two problems:
- The mustard color is not a real TV yellow, as discussed before. TV yellow is much lighter, so even when we find a way to fade the color, it won’t look like a faded TV yellow, but a faded mustard yellow. We can’t change this easily, so we must work with what we have and love it for what it is rather than hating it for what it’s not.
- It’s not nitro lacquer on our Harley Benton but a modern, not-so-thin, ultra-durable poly lacquer. In a technical way, this modern lacquer does a much better job than any vintage nitro stuff regarding protection of the guitar. The downside is that we can’t make poly look like nitro when aging; it will only be an approximation. But again, it is what it is, and we’ll make the best out of it.
If you have the time, exposing the guitar to direct sunlight for some weeks or months will cause a fading of the color to a certain degree. Over the years, I’ve seen the oddest attempts to do such things, including regularly placing the guitar inside a home solarium. Using artificial UV light is also an option but building a well-working construction for such a big object, like a set-neck guitar, is not easy and you’d need a lot of UV lamps for that. Such devices are often used to make yellowed plastic materials look shiny white again. An overspray with the correct color is also an option. but a lighter color on a darker one is always difficult to do—especially with a semi-transparent color like TV yellow. And I doubt it’s worth the time and money. Not everything is doable and this falls into that category. But we’ll do other things to make it look old and cool, so leave the color as it is.
Let’s begin. As usual, grab your steel wool and abrasive cloth to break the shine of the high-gloss lacquer, and don’t forget the backside of the neck. The difference can be seen in Photo 1 (before) and Photo 2 (after).
Aging the Lacquer
This is what a lot of you have been waiting for and today we’ll finally do it: cracking the lacquer!We all know the look of cracked lacquer on vintage guitars, which is part of their special appearance and charm. On vintage guitars this happens over time, the softener disappears, and the paint starts to crack. Here again, facing that our Harley Benton is poly and not nitro-painted, we must follow a different route to get a good result.
Generally, there are two basic methods to do this:
- Mimicking the cracks by using a razor blade to cut the cracks into the paint.
- Using a combination of heat and cold to crack the lacquer.
In both cases this is only the first step. Next, we’ll have to make the cracks more visible, but first things first.
I decided to use the second method: using heat and cold to crack the lacquer. Please note, this will take some time and patience to do it right: It won’t be done in 15 minutes. You don’t need much for this, just a heat gun and several bottles of cooling spray. The process is easy but safety first: Only do this outside, wear gloves and goggles, and place a bucket with cold water or an extinguisher near you … a heat gun gets very hot!
You can’t do this in one step, and you’ll need to work in smaller areas, one by one. Heat up the first area with the heat gun and be careful—you only want to heat up the lacquer and not melt or burn it. If you want to intentionally add some burned spots, a heat gun is the way to go, too. Depending on the type and thickness of the lacquer as well as the power of your heat gun, it can take some time until the lacquer is ready to crack. Start to heat it up from a distance and not with the heat gun directly on the guitar, checking the temperature of the lacquer from time to time with one of your hands. Never put your hand directly under the heat gun! Take the guitar body and your hands away from the gun when you check the temperature. If you feel that it’s not hot enough, keep heating it up until it’s good to go.
Photo 3
Photo 4
There are no rules set in stone because it depends on the things mentioned above. So, you have to try and see what works on your guitar. If you think the lacquer is hot enough, take away the heat gun and immediately spray the heated area with the cooling spray to create a sudden temperature gradient. You’ll likely have to repeat the process several times until the lacquer starts to crack, and usually you can hear when it cracks, which is a good sign. Work your way all over the guitar and crack it area by area. I needed approximately 90 minutes and four bottles of cooling spray until I was finished (Photo 3).
Does it look the same as cracked nitro lacquer? No, it’s not the same cracking pattern because of two reasons. On a nitro-lacquered guitar, the cracking happens because the softener disappears over time, which is a completely different thing. Poly is hard as glass and will never lose its softener. So, the vintage guitars of the future, let’s say in 100 years from now, will look much different compared to today—no more cracks. The second reason is that only in the middle of the spray is the lowest possible temperature not on the edge of the spray. But it’s the same ballpark, so don’t worry.
After you’re done with the entire guitar, let it cool down for some time before we start to make the cracks more visible. Again, there are different ways to do this. I prefer to use a strong black tea or coffee. Warm up the guitar slightly and dip some paper towels into the black tea or coffee before covering the guitar with them. Let them sit there for some hours before you remove them. The moisture will creep into the cracks, coloring them slightly, so they are more visible. This is a permanent process: The cracks will not lose their color again over time. On poly-lacquered guitars, I’ve also seen and tried alternative methods like using Coca-Cola, potassium permanganate, coffee grounds, stains, and more. The tea/coffee method works great and with good results and is, of course, harmless. But feel free to try other methods if you want to experiment, there’s no law against it.
After removing the paper towels, let it dry for some time before removing any residues from the lacquer using a dampish paper towel. Then, heat up the guitar slightly and let it cool down again. And voila, done! You can see the cracks are now brighter in Photo 4.
Congratulations, we are only one step away from finishing our aging project! Next, we’ll add some dings, dongs, and scratches, which is a lot of fun and a great way to individualize your guitar.
That’s it for now. Next month we’ll do another cool guitar mod, so stay tuned. Until then ... keep on modding!
Teatime: How to Age Wood at Home
Matthias Meyer of Bassart Guitars
Hi PG readers,
Did you ever wonder how it’s possible to add a special gray and dark color to the exposed wood on aged guitars? Here is my recommendation for how to do this with some simple household stuff you already have.
You will need: vinegar essence, water, black tea, steel wool, paper coffee filters, and some jars.
First, twitch a good handful of steel wool and put it in a jar. Next, fill up the jar with vinegar essence, close the jar, and let it sit for one or two days. The reaction of the steel wool and the vinegar will result in iron(II) acetate, which you can use as a dye. Use a cone-shaped paper coffee filter to percolate the liquid into a new jar and you hold the panacea in your hands. By adding some water, you can mitigate the dying effect and it’s easy to make some different aging dyes this way, from very dark to light gray.
Now it’s teatime. Make a strong black tea by using 6 to 8 tea bags in a pot, let it cool down, remove the tea bags, and pour the tea in a new jar.
One way of aging the exposed wood is to use the tea first, immediately followed by the iron(II) acetate (wet on wet technique). For a different effect and color, use the tea first and let it dry before applying the iron(II) acetate. Or use both liquids individually without the other one. It all depends on your personal taste and, of course, the wood itself. Before applying these liquids directly to your precious instruments, you should try to practice the process on some wood scraps you have lying around. Different woods react in very different ways and often the aging process needs one or two days before it becomes visible.
I hope you enjoy experimenting with this process. Cheers!
—Matthias “Matti” Meyer
www.bassartguitars.de
StewMac tech guru Erick Coleman on how to give your instrument a sweet new look in five easy steps—sans fancy tools.
You love your guitar. You've been playing it for years, but the time has come to give it a makeover. The color was cool when you bought it (Photo 1), but now you'd like a change.
It's not too difficult to refinish a guitar. More than anything, it's a matter of patience. Taking the time to properly prep the wood and allow appropriate cure times can yield excellent results, even for the first-timer.
There are several types of finish used for guitars. Traditional nitrocellulose finishes are found on many high-end instruments as well as production guitars by Gibson and Martin, just to name a few manufacturers. Harder polyurethane finishes can be found on millions of guitars, including most Fender, Ibanez, and Epiphone models. Some manufacturers are now also using environmentally friendly waterborne finishes that are safer to handle.
For this project, we will be removing an existing polyurethane finish and refinishing the guitar with nitrocellulose lacquer in aerosol cans, for convenience. In addition to changing the appearance, this refin will likely result in a better-sounding instrument as well.
Use warm lacquer, not cold. Pro finishers spray heated lacquer because cold lacquer spatters, requiring extra work to get a level finish.
A guitar with a thin nitro finish will resonate better than one with a hard poly. But nitrocellulose is flammable and hazardous to inhale, so make sure you have a well-ventilated work area and use proper safety precautions, like wearing a respirator mask.
First you'll need to solder together and tape off the north coil finish and south coil finish (this is the series link). Then, here's a list of the items needed along with the StewMac parts numbers and amounts of the products we'll use:
- Hair dryer or heat gun to remove existing finish.
- Putty knife (#4464 and #1287).
- Sandpaper in a variety of grits for wood prep and finish work (#5562).
- Aerosol lacquer (#5886 Sonic Blue x 1, #3881 gloss clear x 3).
- Polishing cloth (#1815 x 2).
- Liquid polishing compounds (#1845 medium, #1846 fine).
- Respirator mask (#5885).
Step 1: Disassemble the guitar
Photo 2
The first step is to take the instrument completely apart, removing all hardware and electronics (Photo 2). Keep all the parts in one place as you remove them so you don't have to hunt them down when you are ready to reassemble the guitar.
Step 2: Strip the existing finish
Photo 3
There are a few different ways to strip a finish. Simply sanding a finish off can be very time-consuming and dirty, and using chemical strippers can be very toxic and messy. I've found the best way to cleanly and easily strip polyurethane finish of this type is to use a hair dryer or heat gun and a flexible putty knife (Photo 3).
Photo 4
Lightly scoring a starting point in the finish with a sharp putty knife will give you a good entry point once the finish is heated. The idea is to soften and lift the finish without burning it, so it is important to keep the gun moving while heating. With the gun set on the lowest setting, start warming up the scored area on the guitar. When you see the finish starting to lift, work the knife underneath it and start removing it (Photo 4).
Photo 5
Once you get under the finish, the rest of the job goes pretty fast. Use care not to damage the wood with the knife or scorch it with your heat source. Remove as much of the finish as possible, including that in the cavities (Photo 5).
Step 3: Prepare the body
When all the finish is removed, it's time to prepare the body for refinishing. Inspect the body and neck for any dings, chips, or other imperfections. Small dents can be steamed out by placing a damp cloth over the dent and applying heat with a soldering iron. (For instructions on steaming out dents, see "Steaming Out Dents in a '71 Medallion Flying V.") Chips will need to be filled.
Photo 6
Once you've inspected the body and checked it for dings and chips, it's time to gather your sandpaper and sanding blocks (Photo 6).
Photo 7
Using a flat backing pad and starting with 120-grit sandpaper, sand the entire body working only in the direction of the grain (Photo 7). Inspect the body to make sure you are removing any traces of finish or sealer left over from the original paint job. After a complete sanding, wipe down the body with a damp cloth to raise the grain. Let it dry, then sand with 220-grit sandpaper. Raise the grain with a damp cloth again and sand a third time, using 320-grit sandpaper. Take your time and do a thorough job during these steps to insure you get a nice flat surface to build your finish on. When you've finished sanding, wipe the body with a naphtha-dampened rag to remove any oils or grease left by your hands. From this point on, wear clean gloves so you won't contaminate the wood.
Step 4: Spraying
Photo 8
It's now time to spray your finish. For this you will need some kind of handle for holding your guitar and a place to hang it to dry. Pieces of scrap wood make good handles for holding the body while you spray (Photo 8). They also give you a way to hang the body while it cures. Here's where being especially patient will pay off. A professional nitrocellulose finishing job takes weeks to complete, but the end result is something you can be proud of!
Photo 9
Tip: Use warm lacquer, not cold. Pro finishers spray heated lacquer because cold lacquer spatters, requiring extra work to get a level finish. For best results, heat your cans in a sink of warm water before spraying (Photo 9).
Day One
Photo 10
Day one. Spray an initial light misting or tack coat (Photo 10), followed several minutes later by a heavier wet coat. The tack coat gives the wet coat better adherence and lessens the chance of a run in the finish. Spray two to three wet coats (but not runny, thick coats) on the body, 90 minutes apart, and let them dry overnight.
Day Two
Using a backing pad on the flat areas, lightly scuff-sand the body with 320-grit sandpaper to knock off the high spots in the finish. Sand just enough to open the finish—don't try to sand out every shiny spot or sunken area in the lacquer at this stage. Clean off all the sanding residue. Spray two to three uniform color coats for complete coverage, allowing 90 minutes between coats.
Day Three
Lightly scuff-sand the finish with 320-grit paper using care not to sand through your color coats, and clean off all the residue. Spray four uniform coats of clear lacquer, one hour between coats. Let the guitar dry overnight.
Tip: If you get a run or drip in the finish, let the surface dry for 24 hours and level-sand the problem area. If you touch wet lacquer, you'll leave a deep impression that will be much more difficult to fix.
Day Four
Lightly scuff-sand the finish with 320-grit paper, leveling out any imperfections in the process, and clean off all the residue. Don't try to sand out all the shiny spots yet. Be particularly careful on the curves of the body. It's easy to sand through the edges. Once again, spray four more coats of clear, 90 minutes apart. The guitar now has six to eight topcoats of clear lacquer. Let the finish dry overnight.
If you get a run or drip in the finish, let the surface dry for 24 hours and level-sand the problem area.
Day Five
Scuff-sand the finish with 320-grit again. This time most of the shiny spots will disappear, leaving a uniformly dull look. Spray four more clear coats, 90 minutes apart, and let dry overnight.
Day Six
Lightly scuff-sand the finish with 600-grit sandpaper, to help the solvent escape. The body should now be left in a warm and dry location for two weeks to let the finish cure.
Step 5: Fine sanding and buffing
Dry-sand the body to a flat, dull sheen with 800-grit sandpaper. Clean the residue from the paper often. Orange-peel texture caused by lacquer shrinkage as the solvents cure out of the finish should be removed, but don't over sand. When all the little shiny low spots in the lacquer have been removed, you're ready to go to the next step, which is wet-sanding.
Photo 11
To bring the finish to a smooth satin surface that's ready for final polishing, wet-sand with 1200-grit micro-finishing paper and water (Photo 11). Excess water and residue should be wiped off the finish with a clean dry soft cloth as you work. Frequently rinse the sandpaper in soapy water to remove hard specks that can scratch the finish.
Tip: Soak the micro-finishing paper in water overnight before use. It will scratch less and last longer. Always keep it wet from then on.
Photo 12
Using soft cloths—a different one for each compound—polish out the fine wet-sanding scratches to a final gloss with medium and then fine liquid polishing compounds (Photo 12).
Photo 13
Once you've polished the body to a high gloss, reassemble your guitar (Photo 13) and get it back in action!
[Updated 9/10/21]